Conference article

Modelling and Simulation of Phase Transition in Compressed Liquefied CO2

Sindre Tosse
Department of Process, Energy and Environment Technology, University College of Southeast Norway, Norway

Per Morten Hansen
Department of Process, Energy and Environment Technology, University College of Southeast Norway, Norway

Knut Vaagsaether
Department of Process, Energy and Environment Technology, University College of Southeast Norway, Norway

Download articlehttp://dx.doi.org/10.3384/ecp17142653

Published in: Proceedings of The 9th EUROSIM Congress on Modelling and Simulation, EUROSIM 2016, The 57th SIMS Conference on Simulation and Modelling SIMS 2016

Linköping Electronic Conference Proceedings 142:95, p. 653-659

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Published: 2018-12-19

ISBN: 978-91-7685-399-3

ISSN: 1650-3686 (print), 1650-3740 (online)

Abstract

A model and solution method for phase transition in compressed lique?ed gases is presented. The model is a two-phase 6-equation model with a common ?ow velocity for the two phases. The numerical method for solving the model is based on the 2. order shock capturing MUSCL-scheme with a HLLC Riemann solver. The van der Waal cubic equation of state is used for closing the set of equations. The phase transition model is based on thermodynamic and mechanical relaxation between the phases. The goal of the work is to present a numerical model capable of resolving the two-phase ?ow situation in the depressurization of a vessel or pipe containing lique?ed CO2. Simulation of expansion and phase transition in pressurized lique?ed CO2 is presented and compared with experimental data. The simulations are with a one dimensional geometry and the experiments are performed in a narrow tube. Wall effects in the experiments are not captured in the simulations. The wave structure seen in the experiments is reproduced by the simulation although not quantitatively. The simulations show that the ?uid is in the metastable region before it undergoes a phase transition. The level of expansion of the metastable liquid shown in the in the simulations is not seen in the experiments.

Keywords

phase transition, lique?ed gas, BLEVE, van der Waal, MUSCL

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